Formation of a highly-ordered rigid multichromophoric 3D supramolecular network by combining ionic and coordination-driven self-assembly

We present here the self-assembly of a green-emitting metallosupramolecular rhomboid into a rigid, highly-ordered 3D multichromophoric network through the mediation of a tetra-anionic violet-blue molecular emitter. Control was obtained on the spatial topology, the electronic energy landscape and the fluorescence polarization of the interacting dipoles.
Chem Commun (Camb) 2016 52:3388-91
Tags: Ions; *Molecular Structure; Proton Magnetic Resonance Spectroscopy; Spectrometry, Fluorescence;
PubMed: 26879596
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